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Issue 52, 2013
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Synergistic dual activation catalysis by palladium nanoparticles for epoxide ring opening with phenols

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Abstract

Synergistic dual activation catalysis has been devised for epoxide phenolysis wherein palladium nanoparticles induce electrophilic activation via coordination with the epoxide oxygen followed by nucleophilic activation through anion–π interaction with the aromatic ring of the phenol, and water (reaction medium) also renders assistance through ‘epoxidephenol’ dual activation.

Graphical abstract: Synergistic dual activation catalysis by palladium nanoparticles for epoxide ring opening with phenols

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Publication details

The article was received on 07 Apr 2013, accepted on 16 May 2013 and first published on 17 May 2013


Article type: Communication
DOI: 10.1039/C3CC42507J
Chem. Commun., 2013,49, 5886-5888

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    Synergistic dual activation catalysis by palladium nanoparticles for epoxide ring opening with phenols

    K. Seth, S. R. Roy, B. V. Pipaliya and A. K. Chakraborti, Chem. Commun., 2013, 49, 5886
    DOI: 10.1039/C3CC42507J

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