Direct observation of the role of lanthanides in stabilizing a ferromagnetic spin orientation in a weak FeIII–FeIII antiferromagnet†
Abstract
[FeIII2LnIII2(OH)2(L1)2(HL2)2(NO3)4(H2O)1½(MeOH)½]·6MeCN (Ln = Y (1), Dy (2); H2L1 =
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* Corresponding authors
a
Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesserstrasse 15, 76128 Karlsruhe, Germany
E-mail:
valeriu.mereacre@kit.edu, annie.powell@kit.edu
Fax: +49 721-608-48142
Tel: +49 721-608-42135
b MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, PR China
c Institute of Nanotechnology, Karlsruhe Institute of Technology, Postfach 3640, 76021 Karlsruhe, Germany
[FeIII2LnIII2(OH)2(L1)2(HL2)2(NO3)4(H2O)1½(MeOH)½]·6MeCN (Ln = Y (1), Dy (2); H2L1 =
H. Xiang, V. Mereacre, Y. Lan, T. Lu, C. E. Anson and A. K. Powell, Chem. Commun., 2013, 49, 7385 DOI: 10.1039/C3CC42416B
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