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Issue 46, 2013
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Salt metathesis in three dimensional metal–organic frameworks (MOFs) with unprecedented hydrolytic regenerability

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Abstract

Eight Zn-based porous (1.2 nm) homochiral MOFs (ValZnX, AlaZnX, X = Cl, Br, HCO2 and CH3CO2) were synthesized which possess extremely rare zeolitic (unh) topology. These MOFs show an unprecedented hydrolytic regenerability. Salt metathesis reaction performed on these 3D MOFs in water resulted in 2D coordination polymers (CPs).

Graphical abstract: Salt metathesis in three dimensional metal–organic frameworks (MOFs) with unprecedented hydrolytic regenerability

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Publication details

The article was received on 12 Mar 2013, accepted on 18 Apr 2013 and first published on 19 Apr 2013


Article type: Communication
DOI: 10.1039/C3CC41842A
Chem. Commun., 2013,49, 5262-5264

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    Salt metathesis in three dimensional metal–organic frameworks (MOFs) with unprecedented hydrolytic regenerability

    T. Kundu, S. C. Sahoo, S. Saha and R. Banerjee, Chem. Commun., 2013, 49, 5262
    DOI: 10.1039/C3CC41842A

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