Issue 46, 2013
From the journal:

Chemical Communications

The first palladium-catalyzed 1,4-addition of terminal alkenes to acrylate esters†

Pei Liu,a   Heng-shan Wang,a   Ying-ming Pan,*a   Wei-long Dai,a   Hong Lianga  and  Zhen-Feng Chen*a  

* Corresponding authors

a Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education of China), School of Chemistry & Chemical Engineering of Guangxi Normal University, Guilin 541004, People's Republic of China
E-mail: panym2004@yahoo.com.cn, chenzfubc@yahoo.com
Fax: +86-773-5803930
Tel: +86-773-5846279

Abstract

A novel and efficient procedure for the synthesis of δ,γ-alkenyl esters with complete E-stereochemistry by the 1,4-addition of alkenes to acrylate esters in the presence of a catalytic amount of palladium chloride has been developed. This method provides a rapid and efficient access to substituted δ,γ-alkenyl esters.

Graphical abstract: The first palladium-catalyzed 1,4-addition of terminal alkenes to acrylate esters

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC41742E
Article type
Communication
Submitted
07 Mar 2013
Accepted
17 Apr 2013
First published
18 Apr 2013

Chem. Commun., 2013,49, 5295-5297

Permissions

Request permissions

The first palladium-catalyzed 1,4-addition of terminal alkenes to acrylate esters

P. Liu, H. Wang, Y. Pan, W. Dai, H. Liang and Z. Chen, Chem. Commun., 2013, 49, 5295 DOI: 10.1039/C3CC41742E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements