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Issue 46, 2013
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The first palladium-catalyzed 1,4-addition of terminal alkenes to acrylate esters

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Abstract

A novel and efficient procedure for the synthesis of δ,γ-alkenyl esters with complete E-stereochemistry by the 1,4-addition of alkenes to acrylate esters in the presence of a catalytic amount of palladium chloride has been developed. This method provides a rapid and efficient access to substituted δ,γ-alkenyl esters.

Graphical abstract: The first palladium-catalyzed 1,4-addition of terminal alkenes to acrylate esters

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Publication details

The article was received on 07 Mar 2013, accepted on 17 Apr 2013 and first published on 18 Apr 2013


Article type: Communication
DOI: 10.1039/C3CC41742E
Chem. Commun., 2013,49, 5295-5297

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    The first palladium-catalyzed 1,4-addition of terminal alkenes to acrylate esters

    P. Liu, H. Wang, Y. Pan, W. Dai, H. Liang and Z. Chen, Chem. Commun., 2013, 49, 5295
    DOI: 10.1039/C3CC41742E

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