Issue 46, 2013
From the journal:

Chemical Communications

The catalytic versatility of low toxicity dialkyltriazolium salts: in situ modification facilitates diametrically opposed catalysis modes in one pot†

Lauren Myles,a   Nicholas Gathergood*b  and  Stephen J. Connon*a  

* Corresponding authors

a School of Chemistry, Centre for Synthesis and Chemical Biology, Trinity Biomedical Sciences Institute, University of Dublin, Trinity College, Dublin 2, Ireland
E-mail: connons@tcd.ie
Fax: +353 16712826

b School of Chemical Sciences and National Institute for Cellular Biotechnology, Dublin City University, Glasnevin, Dublin 9, Ireland
E-mail: Nick.Gathergood@dcu.ie
Fax: +353 17005503

Abstract

The ability of triazolium salts to serve as a precatalyst for both an acid and a powerful base/nucleophile (controlled by additives) has been exploited in a process characterised by a unique in situ catalyst modification strategy.

Graphical abstract: The catalytic versatility of low toxicity dialkyltriazolium salts: in situ modification facilitates diametrically opposed catalysis modes in one pot

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Article information

DOI
https://doi.org/10.1039/C3CC41588K
Article type
Communication
Submitted
01 Mar 2013
Accepted
24 Apr 2013
First published
03 May 2013

Chem. Commun., 2013,49, 5316-5318

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The catalytic versatility of low toxicity dialkyltriazolium salts: in situ modification facilitates diametrically opposed catalysis modes in one pot

L. Myles, N. Gathergood and S. J. Connon, Chem. Commun., 2013, 49, 5316 DOI: 10.1039/C3CC41588K

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