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Issue 35, 2013
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Metal-free, highly efficient organocatalytic amination of benzylic C–H bonds

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Abstract

A new synthetic approach toward direct C–N bond formation through sp3 C–H activation has been developed under metal-free conditions. Both primary and secondary benzylic C–H substrates could react smoothly with various amines to give only mono-amination products with good to excellent yields.

Graphical abstract: Metal-free, highly efficient organocatalytic amination of benzylic C–H bonds

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Article information


Submitted
01 Mar 2013
Accepted
15 Mar 2013
First published
15 Mar 2013

Chem. Commun., 2013,49, 3700-3702
Article type
Communication

Metal-free, highly efficient organocatalytic amination of benzylic C–H bonds

Q. Xue, J. Xie, H. Li, Y. Cheng and C. Zhu, Chem. Commun., 2013, 49, 3700
DOI: 10.1039/C3CC41558A

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