Issue 9, 2013
From the journal:

Chemical Communications

Palladium-catalyzed decarboxylative acylation of O-methyl ketoximes with α-keto acids†

Minyoung Kim,a   Jihye Park,a   Satyasheel Sharma,a   Aejin Kim,a   Eonjeong Park,a   Jong Hwan Kwak,a   Young Hoon Junga  and  In Su Kim*a  

* Corresponding authors

a School of Pharmacy, Sungkyunkwan University, Suwon 440-746, Republic of Korea
E-mail: insukim@skku.edu
Fax: +82 31 292 8800
Tel: +82 31 290 7788

Abstract

A mild, practical and efficient palladium-catalyzed decarboxylative ortho-acylation of O-methyl ketoximes with α-keto acids via C–H bond activation is described. In these reactions, a broad range of O-methyl ketoximes and α-keto acids undergoes the decarboxylative cross-coupling reactions with high selectivities and good tolerance.

Graphical abstract: Palladium-catalyzed decarboxylative acylation of O-methyl ketoximes with α-keto acids

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Article information

DOI
https://doi.org/10.1039/C2CC38433G
Article type
Communication
Submitted
23 Nov 2012
Accepted
03 Dec 2012
First published
04 Dec 2012

Chem. Commun., 2013,49, 925-927

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Palladium-catalyzed decarboxylative acylation of O-methyl ketoximes with α-keto acids

M. Kim, J. Park, S. Sharma, A. Kim, E. Park, J. H. Kwak, Y. H. Jung and I. S. Kim, Chem. Commun., 2013, 49, 925 DOI: 10.1039/C2CC38433G

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