Issue 11, 2013
From the journal:

Chemical Communications

Activation of dichloromethane by a V(iii) thiolate complex: an example of S-based nucleophilic reactivity in an early transition metal thiolate†

Tzu-Tso Chen,‡a   Yu-Sen Chen,‡a   Ya-Ho Chang,a   Jung-Ching Wang,a   Yi-Fang Tsai,a   Gene-Hsiang Lee,b   Tin-Shen Kuoc  and  Hua-Fen Hsu*a  

* Corresponding authors

a Department of Chemistry, National Cheng Kung University, Tainan 701, Taiwan
E-mail: konopka@mail.ncku.edu.tw
Fax: +886-62740552
Tel: +886-62757575-65336

b Department of Chemistry, National Taiwan University, Taipei 116, Taiwan

c Department of Chemistry, National Taiwan Normal University, Taipei 116, Taiwan

Abstract

A VIII thiolate complex activated C–Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a VIII-Cl species (major one) and a VIV binding to a CH2 containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics.

Graphical abstract: Activation of dichloromethane by a V(iii) thiolate complex: an example of S-based nucleophilic reactivity in an early transition metal thiolate

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Article information

DOI
https://doi.org/10.1039/C2CC37801A
Article type
Communication
Submitted
27 Oct 2012
Accepted
17 Dec 2012
First published
17 Dec 2012

Chem. Commun., 2013,49, 1109-1111

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Activation of dichloromethane by a V(III) thiolate complex: an example of S-based nucleophilic reactivity in an early transition metal thiolate

T. Chen, Y. Chen, Y. Chang, J. Wang, Y. Tsai, G. Lee, T. Kuo and H. Hsu, Chem. Commun., 2013, 49, 1109 DOI: 10.1039/C2CC37801A

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