Issue 7, 2013
From the journal:

Chemical Communications

Ruthenium nitronate complexes as tunable catalysts for olefin metathesis and other transformations†

Tomasz Wdowik,a   Cezary Samojłowicz,a   Magdalena Jawiczuk,a   Maura Malińska,b   Krzysztof Woźniakb  and  Karol Grela*a  

* Corresponding authors

a Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, Warsaw, Poland
E-mail: klgrela@gmail.com
Web: http://www.karolgrela.eu/
Fax: +48-22-632-66-81

b Department of Chemistry, Warsaw University, Pasteura 1, Warsaw, Poland

Abstract

Novel ruthenium(II) complexes were obtained as a result of a stoichiometric reaction of Grubbs’ benzylidene second generation catalysts with 3-nitropropene. These stable complexes, formally ruthenaisoxazole N-oxide derivatives, display activity in both metathesis and non-metathetic processes such as cycloisomerisation, isomerisation and transfer hydrogenation.

Graphical abstract: Ruthenium nitronate complexes as tunable catalysts for olefin metathesis and other transformations

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Article information

DOI
https://doi.org/10.1039/C2CC37385H
Article type
Communication
Submitted
09 Oct 2012
Accepted
21 Nov 2012
First published
22 Nov 2012

Chem. Commun., 2013,49, 674-676

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Ruthenium nitronate complexes as tunable catalysts for olefin metathesis and other transformations

T. Wdowik, C. Samojłowicz, M. Jawiczuk, M. Malińska, K. Woźniak and K. Grela, Chem. Commun., 2013, 49, 674 DOI: 10.1039/C2CC37385H

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