Issue 7, 2013
From the journal:

Chemical Communications

Linear and star-shaped naphthalimide-fused pyrazinacenes†‡

Helena Herrera,a   Paula de Echegaray,a   Marta Urdanpilleta,bc   Maria J. Mancheño,a   Elena Mena-Osteritz,*b   Peter Bäuerleb  and  José L. Segura*a  

* Corresponding authors

a Departamento de Quimica Orgánica, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, E-28040 Madrid, Spain
E-mail: segura@quim.ucm.es
Fax: +34 3944103
Tel: +34 3945142

b Inst. for Organic Chemistry II and Advanced Materials, Univ. of Ulm, Albert-Einstein-Allee 11, D-89081 Ulm, Germany
E-mail: elena.mena-osteritz@uni-ulm.de
Fax: +49 731-5022840
Tel: +49 7315022850

c Dept. de Física Aplicada I, Escuela Politécnica de Donostia, Univ. del País Vasco UPV/EHU, Pl. Europa 1, E-20014 Donostia, Spain

Abstract

A novel naphthalimide derivative endowed with a diketone functionality has been synthesized and used to develop a family of highly symmetric, flat, n-type semiconducting naphthalimide-based pyrazinacenes. By changing the symmetry of these compounds and the number of naphthalimide constituents, fine tuning of their electrochemical, photophysical, and morphological properties is achieved.

Graphical abstract: Linear and star-shaped naphthalimide-fused pyrazinacenes

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Article information

DOI
https://doi.org/10.1039/C2CC36791B
Article type
Communication
Submitted
18 Sep 2012
Accepted
23 Nov 2012
First published
23 Nov 2012

Chem. Commun., 2013,49, 713-715

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Linear and star-shaped naphthalimide-fused pyrazinacenes

H. Herrera, P. de Echegaray, M. Urdanpilleta, M. J. Mancheño, E. Mena-Osteritz, P. Bäuerle and J. L. Segura, Chem. Commun., 2013, 49, 713 DOI: 10.1039/C2CC36791B

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