A porous metal–organic framework based on Zn6O2 clusters: chemical stability, gas adsorption properties and solvatochromic behavior

Jiehu Cui; Yizhi Li; Zijian Guo; Hegen Zheng

doi:10.1039/C2CC36713K

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A porous metal–organic framework based on Zn₆O₂ clusters: chemical stability, gas adsorption properties and solvatochromic behavior†

Jiehu Cui,^a Yizhi Li,^a Zijian Guo^a and Hegen Zheng*^a

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* Corresponding authors

^a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, National Laboratory of Microstructures, Nanjing University, Nanjing 210093, P.R. China
E-mail: zhenghg@nju.edu.cn
Fax: +86-25-83314502

Abstract

A highly connected 3D metal–organic framework with tfz-d topology based on Zn₆O₂ clusters and flexible carboxylate ligands has been synthesized. The obtained Zn-MOF shows solvatochromic behavior for fluorescence sensing of small molecules, gas adsorption properties and exceptional chemical stability and might have applications for separation and detection purposes.

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Article information

DOI: https://doi.org/10.1039/C2CC36713K
Article type: Communication
Submitted: 14 Sep 2012
Accepted: 25 Oct 2012
First published: 01 Nov 2012

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Chem. Commun., 2013,49, 555-557

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A porous metal–organic framework based on Zn₆O₂ clusters: chemical stability, gas adsorption properties and solvatochromic behavior

J. Cui, Y. Li, Z. Guo and H. Zheng, Chem. Commun., 2013, 49, 555 DOI: 10.1039/C2CC36713K

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Chemical Communications