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Issue 3, 2013
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Cs4Mo5P2O22: a first Strandberg-type POM with 1D straight chains of polymerized [Mo5P2O23]6− units and moderate second harmonic generation response†

Ying Wang,ab   Shilie Pan,*a   Hongwei Yu,ab   Xin Su,a   Min Zhang,a   Fangfang Zhanga  and  Jian Han*a  
Author affiliations

* Corresponding authors

a Xinjiang Key Laboratory of Electronic Information Materials and Devices, Xinjiang Technical Institute of Physics & Chemistry, Chinese Academy of Sciences, 40-1 South Beijing Road, Urumqi 830011, China
E-mail: slpan@ms.xjb.ac.cn
Tel: +86-991-3674558

b University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

A noncentrosymmetric chiral Strandberg-type polyoxometalate based material, Cs4Mo5P2O22, that contains unusual one dimensional chains constructed from [Mo5P2O23]6− units has been reported. Cs4Mo5P2O22 shows a moderate SHG response, and is phase-matchable.

Graphical abstract: Cs4Mo5P2O22: a first Strandberg-type POM with 1D straight chains of polymerized [Mo5P2O23]6− units and moderate second harmonic generation response

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Article information

https://doi.org/10.1039/C2CC36354B
Submitted
31 Aug 2012
Accepted
24 Oct 2012
First published
25 Oct 2012
Chem. Commun., 2013,49, 306-308
Article type
Communication
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Cs4Mo5P2O22: a first Strandberg-type POM with 1D straight chains of polymerized [Mo5P2O23]6− units and moderate second harmonic generation response

Y. Wang, S. Pan, H. Yu, X. Su, M. Zhang, F. Zhang and J. Han, Chem. Commun., 2013, 49, 306
DOI: 10.1039/C2CC36354B

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