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Issue 21, 2013
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Green synthesis of carbon dots with down- and up-conversion fluorescent properties for sensitive detection of hypochlorite with a dual-readout assay

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Abstract

High quality carbon dots (C-dots) with down- and up-conversion fluorescence have been synthesized through low-temperature carbonization using sweet pepper as the carbon source. The C-dots with a quantum yield (QY) of 19.3% exhibit superior photophysical properties, for example, narrow and symmetric emission spectra, large stock shifts, resistance to photobleaching, and excitation-dependent fluorescence behavior. The excellent C-dots serve as useful fluorescent probes for hypochlorite (ClO) detection by both down- and up-conversion fluorescence. Two consecutive linear ranges allow a wide determination of ClO concentrations with a low detection limit of 0.05 μmol L−1 and 0.06 μmol L−1 (S/N = 3) for down- and up-conversion fluorescence measurements, respectively. The proposed detection method is advantageous because it is simple, sensitive, dual-signalling model and low-cost and has potential extensive applications in environmental and biological assays.

Graphical abstract: Green synthesis of carbon dots with down- and up-conversion fluorescent properties for sensitive detection of hypochlorite with a dual-readout assay

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Publication details

The article was received on 21 May 2013, accepted on 05 Aug 2013 and first published on 05 Aug 2013


Article type: Paper
DOI: 10.1039/C3AN01003A
Citation: Analyst, 2013,138, 6551-6557
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    Green synthesis of carbon dots with down- and up-conversion fluorescent properties for sensitive detection of hypochlorite with a dual-readout assay

    B. Yin, J. Deng, X. Peng, Q. Long, J. Zhao, Q. Lu, Q. Chen, H. Li, H. Tang, Y. Zhang and S. Yao, Analyst, 2013, 138, 6551
    DOI: 10.1039/C3AN01003A

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