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Issue 8, 2012
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Encapsulation of a ‘naked’ Br anion in a polyoxotitanate host

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Solvothermal reaction of Ti(OiPr)4 with CoBr2 in iPrOH at 150 °C gives the ion-separated compound [Ti12O15(OiPr)17]+[(BrCo)6Ti15O24(OiPr)18(Br)], the heterometallic Ti15Co6 anion of which contains a Br ion trapped within a polyoxotitanate shell. This arrangement provides evidence of new host–guest chemistry in this area.

Graphical abstract: Encapsulation of a ‘naked’ Br− anion in a polyoxotitanate host

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The article was received on 15 Feb 2012, accepted on 01 May 2012 and first published on 03 May 2012

Article type: Edge Article
DOI: 10.1039/C2SC20193C
Citation: Chem. Sci., 2012,3, 2470-2473
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    Encapsulation of a ‘naked’ Br anion in a polyoxotitanate host

    Y. Lv, J. Willkomm, A. Steiner, L. Gan, E. Reisner and D. S. Wright, Chem. Sci., 2012, 3, 2470
    DOI: 10.1039/C2SC20193C

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