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Issue 5, 2012
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Remarkably high-temperature spin transition exhibited by new 2D metal–organic frameworks

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Abstract

Highly stable two-dimensional metal–organic frameworks, 2[FeII(L)2] (HL = 3-(2-pyridyl)-5-(3-pyridyl)-1,2,4-triazole (1) and 3-(3-methyl-2-pyridyl)-5-(3-pyridyl)-1,2,4-triazole (2), display well defined two-step spin crossover properties at remarkably high temperatures, namely, Tc1 = 329 K, Tc2 = 501 K for 1 and Tc1 = 351 K, Tc2 = 520 K for 2, which are the highest critical temperatures reported so far.

Graphical abstract: Remarkably high-temperature spin transition exhibited by new 2D metal–organic frameworks

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Supplementary files

Article information


Submitted
15 Nov 2011
Accepted
29 Jan 2012
First published
31 Jan 2012

Chem. Sci., 2012,3, 1629-1633
Article type
Edge Article

Remarkably high-temperature spin transition exhibited by new 2D metal–organic frameworks

X. Bao, P. Guo, W. Liu, J. Tucek, W. Zhang, J. Leng, X. Chen, I. Gural'skiy, L. Salmon, A. Bousseksou and M. Tong, Chem. Sci., 2012, 3, 1629
DOI: 10.1039/C2SC00924B

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