Jump to main content
Jump to site search
Publishing
Advanced

Issue 5, 2012
Previous Article Next Article

Remarkably high-temperature spin transition exhibited by new 2D metal–organic frameworks

Xin Bao,a  Peng-Hu Guo,a  Wei Liu,a  Jiri Tucek,b  Wei-Xiong Zhang,a  Ji-Dong Leng,a  Xiao-Ming Chen,a  Il'ya Gural'skiy,c  Lionel Salmon,c  Azzedine Bousseksouc  and  Ming-Liang Tong*a 
Author affiliations

* Corresponding authors

a Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry & Chemical Engineering, Sun Yat-Sen University, 510275 Guangzhou, P. R. China
E-mail: tongml@mail.sysu.edu.cn
Fax: (+)86 20 8411-2245

b Regional Centre of Advanced Technologies and Materials, Department of Experimental Physics, Faculty of Science, Palacky University, Slechtitelu 11, 783 71 Olomouc, Czech Republic

c Laboratoire de Chimie de Coordination, CNRS, 31077 Toulouse, France

Abstract

Highly stable two-dimensional metal–organic frameworks, 2∞[FeII(L)2] (HL = 3-(2-pyridyl)-5-(3-pyridyl)-1,2,4-triazole (1) and 3-(3-methyl-2-pyridyl)-5-(3-pyridyl)-1,2,4-triazole (2), display well defined two-step spin crossover properties at remarkably high temperatures, namely, Tc1 = 329 K, Tc2 = 501 K for 1 and Tc1 = 351 K, Tc2 = 520 K for 2, which are the highest critical temperatures reported so far.

Graphical abstract: Remarkably high-temperature spin transition exhibited by new 2D metal–organic frameworks

Back to tab navigation
Download options Please wait...

Supplementary files

Publication details

The article was received on 15 Nov 2011, accepted on 29 Jan 2012 and first published on 31 Jan 2012


Article type: Edge Article
DOI: 10.1039/C2SC00924B
Citation: Chem. Sci., 2012,3, 1629-1633
  •   Request permissions

    Remarkably high-temperature spin transition exhibited by new 2D metal–organic frameworks

    X. Bao, P. Guo, W. Liu, J. Tucek, W. Zhang, J. Leng, X. Chen, I. Gural'skiy, L. Salmon, A. Bousseksou and M. Tong, Chem. Sci., 2012, 3, 1629
    DOI: 10.1039/C2SC00924B

    If you are not the author of this article and you wish to reproduce material from it in a third party non-RSC publication you must formally request permission using Copyright Clearance Center. Go to our Instructions for using Copyright Clearance Center page for details.

    Authors contributing to RSC publications (journal articles, books or book chapters) do not need to formally request permission to reproduce material contained in this article provided that the correct acknowledgement is given with the reproduced material.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      Reproduced from Ref. XX with permission from the Centre National de la Recherche Scientifique (CNRS) and The Royal Society of Chemistry.
    • For reproduction of material from PCCP:
      Reproduced from Ref. XX with permission from the PCCP Owner Societies.
    • For reproduction of material from PPS:
      Reproduced from Ref. XX with permission from the European Society for Photobiology, the European Photochemistry Association, and The Royal Society of Chemistry.
    • For reproduction of material from all other RSC journals and books:
      Reproduced from Ref. XX with permission from The Royal Society of Chemistry.

    If the material has been adapted instead of reproduced from the original RSC publication "Reproduced from" can be substituted with "Adapted from".

    In all cases the Ref. XX is the XXth reference in the list of references.

    If you are the author of this article you do not need to formally request permission to reproduce figures, diagrams etc. contained in this article in third party publications or in a thesis or dissertation provided that the correct acknowledgement is given with the reproduced material.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      [Original citation] - Reproduced by permission of The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC
    • For reproduction of material from PCCP:
      [Original citation] - Reproduced by permission of the PCCP Owner Societies
    • For reproduction of material from PPS:
      [Original citation] - Reproduced by permission of The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC
    • For reproduction of material from all other RSC journals:
      [Original citation] - Reproduced by permission of The Royal Society of Chemistry

    If you are the author of this article you still need to obtain permission to reproduce the whole article in a third party publication with the exception of reproduction of the whole article in a thesis or dissertation.

    Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Search articles by author

Spotlight

Advertisements