Issue 2, 2012
From the journal:

Chemical Science

Preparation of cationic cobaltoceniumpolymers and block copolymers by “living” ring-opening metathesispolymerization†

Lixia Ren,a   Jiuyang Zhang,a   Xiaolong Bai,a   Christopher G. Hardy,a   Ken D. Shimizua  and  Chuanbing Tang*a  

* Corresponding authors

a Department of Chemistry and Biochemistry and Nanocenter, University of South Carolina, Columbia, SC, United States
E-mail: tang.c@chem.sc.edu
Fax: +01-803-777-8100
Tel: +01-803-777-3628

Abstract

We report a robust synthetic strategy to prepare high molecular weight side-chain cationic cobaltocenium-containing polymers and block copolymers via ring-opening metathesis polymerization. All polymerizations were extremely fast with high yields (∼100%) under open air conditions at room temperature and followed a living and controlled manner.

Graphical abstract: Preparation of cationic cobaltocenium polymers and block copolymers by “living” ring-opening metathesis polymerization

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C1SC00783A
Article type
Edge Article
Submitted
11 Oct 2011
Accepted
09 Nov 2011
First published
10 Nov 2011

Chem. Sci., 2012,3, 580-583

Permissions

Request permissions

Preparation of cationic cobaltocenium polymers and block copolymers by “living” ring-opening metathesis polymerization

L. Ren, J. Zhang, X. Bai, C. G. Hardy, K. D. Shimizu and C. Tang, Chem. Sci., 2012, 3, 580 DOI: 10.1039/C1SC00783A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements