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Issue 28, 2012
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Preparation of endohedral fullerene containing lithium (Li@C60) and isolation as pure hexafluorophosphate salt ([Li+@C60][PF6])

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Abstract

A synthetic protocol for endohedral fullerene containing lithium (Li@C60), as well as the synthesis, characterization, and properties of its chemically oxidized derivative [Li+@C60][PF6] are reported in full. Simultaneous deposition of Li plasma and C60 produces a mixture containing Li@C60 and C60. Strong intermolecular attraction between Li@C60 and C60 has prevented their separation, but this obstacle was surmounted by selective chemical oxidation of Li@C60, which led to the isolation of a substantial amount of pure [Li+@C60][PF6]. For this purpose, an HPLC technique using an electrolyte in the mobile phase was effective in purifying the ionic metallofullerene. [Li+@C60][PF6] was stable in air and, compared with [Li+@C60][SbCl6], was more stable to moisture and various chemicals. [Li+@C60][PF6] holds promise for practical applications. The spectroscopic data (MS, 7Li and 13C NMR, UV-vis, and IR) and electrochemical data for [Li+@C60][PF6] are disclosed. In addition, the high electron affinity of [Li+@C60][PF6] is discussed.

Graphical abstract: Preparation of endohedral fullerene containing lithium (Li@C60) and isolation as pure hexafluorophosphate salt ([Li+@C60][PF6−])

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Supplementary files

Article information


Submitted
21 Jun 2012
Accepted
10 Sep 2012
First published
13 Sep 2012

RSC Adv., 2012,2, 10624-10631
Article type
Paper

Preparation of endohedral fullerene containing lithium (Li@C60) and isolation as pure hexafluorophosphate salt ([Li+@C60][PF6])

H. Okada, T. Komuro, T. Sakai, Y. Matsuo, Y. Ono, K. Omote, K. Yokoo, K. Kawachi, Y. Kasama, S. Ono, R. Hatakeyama, T. Kaneko and H. Tobita, RSC Adv., 2012, 2, 10624
DOI: 10.1039/C2RA21244G

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