High performance low temperature solid oxidefuel cells with novel electrode architecture

Abstract

In this study, we have fabricated high performance low temperature solid oxide fuel cells (LT-SOFCs) with both acicular anodes and cathodes with thin Gd-doped ceria (GDC) electrolyte film. The acicular Ni-Gd_0.1Ce_0.9O_2−δ (Ni-GDC) anode was prepared using freeze drying tape casting, while the hierarchically porous cathode with nano-size Sm_0.5Sr_0.5CoO₃ (SSC) particles covering an acicular GDC skeleton was prepared by a combination of freeze drying tape casting and self-rising approaches. The acicular electrodes with 5–200 μm pores/channels enhance mass transport, while SSC particles of about 50 nm in the cathode promote electrochemical reactions. Cells which have this novel electrode architecture show a significantly high power output of 1.44 W cm⁻² and an extremely low cell polarization resistance of 0.0379 Ω cm² at 600 °C.