Issue 23, 2012

A simple diamine as ligand in iron-catalyzed regioselective allylic alkylation

Abstract

A simple and efficient diamine was found to be an efficient ligand for the iron-catalyzed regioselective allylic alkylation between various allyl carbonates and nucleophiles, affording excellent yields and good regioselectivity (up to 94% and >20 : 1).

Graphical abstract: A simple diamine as ligand in iron-catalyzed regioselective allylic alkylation

Supplementary files

Article information

Article type
Communication
Submitted
01 Aug 2012
Accepted
02 Aug 2012
First published
02 Aug 2012

RSC Adv., 2012,2, 8627-8630

A simple diamine as ligand in iron-catalyzed regioselective allylic alkylation

C. Yu, A. Zhou and J. He, RSC Adv., 2012, 2, 8627 DOI: 10.1039/C2RA21646A

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