Structure of a large colloidal crystal – controlling orientation and three-dimensional order

Abstract

The three-dimensional crystal structure of charge stabilised polystyrene latex in deionised water was investigated by small-angle neutron diffraction. Crystallisation with a grain size of approximately 1 × 1 cm² was observed when the sample was flowed gently in to a 2 mm path cell. Bragg scattering peaks arising from the structure were observed under rotation about three perpendicular axes of the sample. The diffraction patterns indicate clearly that there is a cubic close packed structure with a 110 axis perpendicular to the cell wall. Rotations in small steps show large changes and indicate that the crystal is well oriented and has three-dimensional order. The crystal orientation was controlled by the meniscus and direction of flow when filling the cell.