Issue 21, 2012
From the journal:

RSC Advances

Organocatalytic domino reaction of salicyl N-thiophosphoryl imines and methyl vinyl ketone initiated by an aza-MBH reaction with bifunctional phosphine catalysts†

Xiangtai Meng,a   Peizhong Xie,a   You Huang*a  and  Ruyu Chena  

* Corresponding authors

a State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin, China
E-mail: hyou@nankai.edu.cn
Fax: (+86)22-23503627
Tel: (+86)22-23503159

Abstract

We report two domino reactions between salicyl N-thiophosphoryl imines and methyl vinyl ketone catalyzed by bifunctional phosphine catalysts and DBU. These reactions provide two simple and efficient methods to construct chromans and chromens under mild conditions, respectively.

Graphical abstract: Organocatalytic domino reaction of salicyl N-thiophosphoryl imines and methyl vinyl ketone initiated by an aza-MBH reaction with bifunctional phosphine catalysts

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Article information

DOI
https://doi.org/10.1039/C2RA20823G
Article type
Paper
Submitted
15 Mar 2012
Accepted
27 Jun 2012
First published
27 Jun 2012

RSC Adv., 2012,2, 8104-8109

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Organocatalytic domino reaction of salicyl N-thiophosphoryl imines and methyl vinyl ketone initiated by an aza-MBH reaction with bifunctional phosphine catalysts

X. Meng, P. Xie, Y. Huang and R. Chen, RSC Adv., 2012, 2, 8104 DOI: 10.1039/C2RA20823G

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