Issue 8, 2012
From the journal:

RSC Advances

Solvent-free isomerization of allylic alcohols catalyzed by a rhodium catalyst-organic framework†

Elizabeth G. Corkum,a   Suneth Kalapugama,a   Michael J. Hassa  and  Steven H. Bergens*a  

* Corresponding authors

a Department of Chemistry, University of Alberta, Edmonton, Alberta, Canada T6G 2G2
E-mail: steve.bergens@ualberta.ca
Fax: (780) 493-8231
Tel: (780) 492-9703

Abstract

The solvent-free isomerization of allylic alcohols is reported using an immobilized rhodium catalyst-organic framework (COF) synthesized from alternating ring-opening metathesis polymerization (altROMP) assembly. The catalyst provided TONs as high as 38 000, with catalyst loadings as low as 0.0025 mol% for the isomerizations. Kinetic resolution of starting allylic alcohol 5 was also observed.

Graphical abstract: Solvent-free isomerization of allylic alcohols catalyzed by a rhodium catalyst-organic framework

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Article information

DOI
https://doi.org/10.1039/C2RA20197F
Article type
Paper
Submitted
02 Feb 2012
Accepted
07 Feb 2012
First published
07 Feb 2012

RSC Adv., 2012,2, 3473-3476

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Solvent-free isomerization of allylic alcohols catalyzed by a rhodium catalyst-organic framework

E. G. Corkum, S. Kalapugama, M. J. Hass and S. H. Bergens, RSC Adv., 2012, 2, 3473 DOI: 10.1039/C2RA20197F

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