Electrochemical hydrogen storage properties of a non-equilibrium Ti2Ni alloy

Abstract

A crystalline Ti₂Ni alloy was mechanically milled and subsequently annealed to form a non-equilibrium Ti₂Ni alloy. This non-equilibrium structure could restrain the formation of irreversible metal hydride during charging. Consequently, we demonstrated that the alloy had a discharge capacity of 336 mAh g⁻¹, which was much higher than those of other Ti₂Ni alloys reported in the literature and also higher than that of the commercial LaNi₅–based alloy. An electrochemical hydrogen absorption–desorption mechanism of the alloy during cycling is also presented.