Issue 3, 2012
From the journal:

Polymer Chemistry

Aqueous RAFT/MADIX polymerisation of vinylphosphonic acid†

Issam Blidi,a   Roland Geagea,a   Olivier Coutelier,a   Stéphane Mazières,a   Frédéric Violleaub  and  Mathias Destarac*a  

* Corresponding authors

a Université Paul Sabatier, Laboratoire Hétérochimie Fondamentale et Appliquée, UMR-CNRS 5069, Bât 2R1, 118, route de Narbonne, Toulouse Cedex 9, France
E-mail: destarac@chimie.ups-tlse.fr

b Université de Toulouse, Ecole d'Ingénieurs de Purpan, UPSP/DGER 115, 75, voie du TOEC, BP 57611, Toulouse Cedex 03, France
E-mail: frederic.violleau@purpan.fr

Abstract

RAFT/MADIX polymerisation of vinylphosphonic acid (VPA) was controlled in water with an O-ethyl xanthate transfer agent. This represents the first example of reversible deactivation radical polymerisation of a monomer bearing an unprotected phosphonic acid function. Hence, macromolecular engineering of polyphosphonates can now be envisioned by directly polymerising VPA in water.

Graphical abstract: Aqueous RAFT/MADIX polymerisation of vinylphosphonic acid

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Article information

DOI
https://doi.org/10.1039/C2PY00541G
Article type
Communication
Submitted
10 Nov 2011
Accepted
16 Dec 2011
First published
11 Jan 2012

Polym. Chem., 2012,3, 609-612

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Aqueous RAFT/MADIX polymerisation of vinylphosphonic acid

I. Blidi, R. Geagea, O. Coutelier, S. Mazières, F. Violleau and M. Destarac, Polym. Chem., 2012, 3, 609 DOI: 10.1039/C2PY00541G

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