Issue 2, 2012
From the journal:

Polymer Chemistry

Branching out with aminals: microporous organic polymers from difunctional monomers†

Andrea Laybourn,a   Robert Dawson,a   Rob Clowes,a   Jonathan A. Iggo,a   Andrew I. Cooper,a   Yaroslav Z. Khimyak‡*a  and  Dave J. Adams*a  

* Corresponding authors

a Department of Chemistry, University of Liverpool, Crown Street, Liverpool, U.K
E-mail: djadams@liv.ac.uk, khimyak@liv.ac.uk

Abstract

Microporous organic polymers (MOPs) have been prepared via one-pot polycondensation reactions between aldehydes and amines. Primary amines were reacted with imines to produce porous polymers from A2 + B2 monomer combinations. The resulting networks exhibit BET surface areas in the range 500ā€“600 m2 gāˆ’1. This approach opens up the possibility of synthesising MOPs using readily-available and inexpensive precursors.

Graphical abstract: Branching out with aminals: microporous organic polymers from difunctional monomers

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Article information

DOI
https://doi.org/10.1039/C2PY00506A
Article type
Paper
Submitted
27 Oct 2011
Accepted
04 Dec 2011
First published
22 Dec 2011

Polym. Chem., 2012,3, 533-537

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Branching out with aminals: microporous organic polymers from difunctional monomers

A. Laybourn, R. Dawson, R. Clowes, J. A. Iggo, A. I. Cooper, Y. Z. Khimyak and D. J. Adams, Polym. Chem., 2012, 3, 533 DOI: 10.1039/C2PY00506A

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