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Issue 12, 2012
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Direct O-glycosidation of resin bound thioglycosides

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Abstract

The application of the safety-catch linker concept to solid-phase glycoconjugate synthesis is described. The process allows for direct conjugation of resin bound glycans to complex aglycones during cleavage. Large excesses of either coupling partner are not required, and even very hindered alcohols serve as acceptors in the reaction.

Graphical abstract: Direct O-glycosidation of resin bound thioglycosides

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Supplementary files

Article information


Submitted
08 Nov 2011
Accepted
19 Dec 2011
First published
20 Dec 2011

Org. Biomol. Chem., 2012,10, 2373-2376
Article type
Communication

Direct O-glycosidation of resin bound thioglycosides

S. H. Nguyen, A. H. Trotta, J. Cao, T. J. Straub and C. S. Bennett, Org. Biomol. Chem., 2012, 10, 2373 DOI: 10.1039/C2OB06883D

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