Issue 39, 2012
From the journal:

Organic & Biomolecular Chemistry

Versatile approach to α-alkoxy carbamate synthesis and stimulus-responsive alcohol release†

R. Adam Moseya  and  Paul E. Floreancig*a  

* Corresponding authors

a Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA
E-mail: florean@pitt.edu
Fax: +1 412-624-8626
Tel: +1 412-624-8727

Abstract

A series of α-alkoxy carbamates that cleave under mild conditions to release alcohols has been synthesized through a multicomponent process. The relationship between structural features in these compounds and the rate of alcohol release in the presence of basic hydrogen peroxide has been studied. The preparation of carbamates that cleave under other conditions has been demonstrated.

Graphical abstract: Versatile approach to α-alkoxy carbamate synthesis and stimulus-responsive alcohol release

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Article information

DOI
https://doi.org/10.1039/C2OB26571K
Article type
Paper
Submitted
09 Jul 2012
Accepted
14 Aug 2012
First published
30 Aug 2012

Org. Biomol. Chem., 2012,10, 7980-7985

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Versatile approach to α-alkoxy carbamate synthesis and stimulus-responsive alcohol release

R. A. Mosey and P. E. Floreancig, Org. Biomol. Chem., 2012, 10, 7980 DOI: 10.1039/C2OB26571K

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