Issue 13, 2012

A heterotrimetallic Pd–Sm–Pd complex for asymmetric Friedel–Crafts alkylations of pyrroles with nitroalkenes

Abstract

Catalytic asymmetric Friedel–Crafts alkylations of pyrroles and nitroalkenes were carried out by using a novel heterotrimetallic Pd–Sm–Pd catalyst based on a simple chiral ligand 1, to give the adducts with high yields and up to 93% ee.

Graphical abstract: A heterotrimetallic Pd–Sm–Pd complex for asymmetric Friedel–Crafts alkylations of pyrroles with nitroalkenes

Supplementary files

Article information

Article type
Communication
Submitted
11 Jan 2012
Accepted
02 Feb 2012
First published
06 Feb 2012

Org. Biomol. Chem., 2012,10, 2534-2536

A heterotrimetallic Pd–Sm–Pd complex for asymmetric Friedel–Crafts alkylations of pyrroles with nitroalkenes

G. Zhang, Org. Biomol. Chem., 2012, 10, 2534 DOI: 10.1039/C2OB25074H

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