Issue 12, 2012
From the journal:

Organic & Biomolecular Chemistry

Intramolecular iron(ii)-catalyzed aminobromination of allylN-tosyloxycarbamates†

Takuma Kamon,a   Daisuke Shigeoka,a   Tetsuaki Tanakaa  and  Takehiko Yoshimitsu*a  

* Corresponding authors

a Graduate School of Pharmaceutical Sciences, Osaka University, 1-6 Yamadaoka, Suita, Osaka 565-0871, Japan
E-mail: yoshimit@phs.osaka-u.ac.jp
Fax: +81-6-6879-8214
Tel: +81-6-6879-8213

Abstract

Allyl N-tosyloxycarbamates are found to be catalytically transformed into β-brominated oxazolidinones with FeBr2/n-Bu4NBr in t-BuOH.

Graphical abstract: Intramolecular iron(ii)-catalyzed aminobromination of allyl N-tosyloxycarbamates

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Article information

DOI
https://doi.org/10.1039/C2OB07190H
Article type
Communication
Submitted
29 Dec 2011
Accepted
30 Jan 2012
First published
21 Feb 2012

Org. Biomol. Chem., 2012,10, 2363-2365

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Intramolecular iron(II)-catalyzed aminobromination of allyl N-tosyloxycarbamates

T. Kamon, D. Shigeoka, T. Tanaka and T. Yoshimitsu, Org. Biomol. Chem., 2012, 10, 2363 DOI: 10.1039/C2OB07190H

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