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Issue 13, 2012
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Asymmetric catalytic Mannich-type reaction of hydrazones with difluoroenoxysilanes using imidazoline-anchored phosphine ligand–zinc(ii) complexes

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Abstract

Asymmetric Mannich-type reaction of hydrazones with difluoroenoxysilanes using chiral zinc(II)–imidazoline–phosphine complexes as catalysts have been established, giving the corresponding adducts in good to excellent enantioselectivity and chemical yields under mild conditions.

Graphical abstract: Asymmetric catalytic Mannich-type reaction of hydrazones with difluoroenoxysilanes using imidazoline-anchored phosphine ligand–zinc(ii) complexes

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Article information


Submitted
01 Dec 2011
Accepted
06 Jan 2012
First published
09 Jan 2012

Org. Biomol. Chem., 2012,10, 2509-2513
Article type
Communication

Asymmetric catalytic Mannich-type reaction of hydrazones with difluoroenoxysilanes using imidazoline-anchored phosphine ligand–zinc(II) complexes

Z. Yuan, L. Mei, Y. Wei, M. Shi, P. V. Kattamuri, P. McDowell and G. Li, Org. Biomol. Chem., 2012, 10, 2509
DOI: 10.1039/C2OB07022G

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