Pd        nanoparticle catalysed one-pot sequential Heck and Suzuki couplings of bromo-chloroarenes in ionic liquids and water

Pietro Cotugno; Antonio Monopoli; Francesco Ciminale; Nicola Cioffi; Angelo Nacci

doi:10.1039/C1OB06385E

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Pd nanoparticle catalysed one-pot sequential Heck and Suzuki couplings of bromo-chloroarenes in ionic liquids and water†‡

Pietro Cotugno,^a Antonio Monopoli,*^a Francesco Ciminale,^a Nicola Cioffi^a and Angelo Nacci*^ab

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* Corresponding authors

^a Department of Chemistry, Università degli Studi di Bari Aldo Moro, Via Orabona 4, Bari, Italy
E-mail: nacci@chimica.uniba.it, antomono@libero.it
Fax: +39.080.5442129
Tel: +39.080.5442499

^b CNR-ICCOM, Department of Chemistry, Università degli Studi di Bari Aldo Moro, Via Orabona 4, Bari, Italy

Abstract

Pd nanoparticles generated in green reaction media (viz. ionic liquids and water) catalyze the one-pot sequential Heck and Suzuki coupling reactions of bromo-chloroarenes to afford unsymmetrically substituted arenes in good yields.

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Article information

DOI: https://doi.org/10.1039/C1OB06385E
Article type: Paper
Submitted: 26 May 2011
Accepted: 18 Oct 2011
First published: 20 Oct 2011

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Org. Biomol. Chem., 2012,10, 808-813

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Pd nanoparticle catalysed one-pot sequential Heck and Suzuki couplings of bromo-chloroarenes in ionic liquids and water

P. Cotugno, A. Monopoli, F. Ciminale, N. Cioffi and A. Nacci, Org. Biomol. Chem., 2012, 10, 808 DOI: 10.1039/C1OB06385E

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Organic & Biomolecular Chemistry