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Issue 8, 2012
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Synthesis of a sterically modulated pyridine–NHC palladium complex and its reactivity towards ethylene

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Abstract

A new cationic pyridine-carbene palladium complex has been prepared that features a C,N-bidentate coordinating ligand with a shielded pyridine and a sterically less protected carbene moiety; evaluation of this complex in ethylene polymerization revealed competitive reductive elimination processes and provides guidelines for further catalyst design.

Graphical abstract: Synthesis of a sterically modulated pyridine–NHC palladium complex and its reactivity towards ethylene

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Article information


Submitted
16 Apr 2012
Accepted
23 May 2012
First published
30 May 2012

New J. Chem., 2012,36, 1552-1555
Article type
Letter

Synthesis of a sterically modulated pyridine–NHC palladium complex and its reactivity towards ethylene

V. Khlebnikov, A. Meduri, H. Mueller-Bunz, B. Milani and M. Albrecht, New J. Chem., 2012, 36, 1552
DOI: 10.1039/C2NJ40287D

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