Issue 8, 2012
From the journal:

New Journal of Chemistry

Synthesis of a sterically modulated pyridine–NHC palladium complex and its reactivity towards ethylene†

Vsevolod Khlebnikov,a   Angelo Meduri,b   Helge Mueller-Bunz,a   Barbara Milani*b  and  Martin Albrecht*a  

* Corresponding authors

a School of Chemistry and Chemical Biology, University College Dublin, Belfield, Dublin 4, Ireland
E-mail: martin.albrecht@ucd.ie
Fax: +353-17162501
Tel: +353-17162504

b Dipartimento di Scienze Chimiche e Farmaceutiche, Università di Trieste, Via Licio Giorgieri 1, 34127 Trieste, Italy
E-mail: milaniba@units.it

Abstract

A new cationic pyridine-carbene palladium complex has been prepared that features a C,N-bidentate coordinating ligand with a shielded pyridine and a sterically less protected carbene moiety; evaluation of this complex in ethylene polymerization revealed competitive reductive elimination processes and provides guidelines for further catalyst design.

Graphical abstract: Synthesis of a sterically modulated pyridine–NHC palladium complex and its reactivity towards ethylene

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Article information

DOI
https://doi.org/10.1039/C2NJ40287D
Article type
Letter
Submitted
16 Apr 2012
Accepted
23 May 2012
First published
30 May 2012

New J. Chem., 2012,36, 1552-1555

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Synthesis of a sterically modulated pyridine–NHC palladium complex and its reactivity towards ethylene

V. Khlebnikov, A. Meduri, H. Mueller-Bunz, B. Milani and M. Albrecht, New J. Chem., 2012, 36, 1552 DOI: 10.1039/C2NJ40287D

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