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Issue 10, 2012
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Suberin isolation from cork using ionic liquids: characterisation of ensuing products

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Abstract

Cholinium alkanoates, a class of benign ionic liquids, were demonstrated to efficiently extract suberin domains from cork. A detailed characterisation of the extracted material has yet to be attained. In the present study the significance of the alkylic chain length of the anion and the ionic liquid's basicity was investigated. The results obtained emphasise cholinium hexanoate's selection; it proved to be a straightforward process, also ensuring the recyclability and reusability of the ionic liquid. The extracted suberinic material has been thoroughly characterised for the first time by ATR-FTIR, NMR, GC-MS and thermal analyses. Data showed that it is mainly composed of oligomeric or polymeric aliphatic esterified structures, resulting from suberin partial cleavage. More than 40 wt% of the extracted suberinic material was found to be cross-linked. Even though, the composing monomeric units were similar to those usually identified in suberin samples obtained by the conventional extraction processes. These data pave the way for advanced studies of suberin monomers/oligomers as building-blocks for the development of novel biopolymers and biomaterials.

Graphical abstract: Suberin isolation from cork using ionic liquids: characterisation of ensuing products

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Supplementary files

Article information


Submitted
25 May 2012
Accepted
08 Jul 2012
First published
11 Jul 2012

New J. Chem., 2012,36, 2014-2024
Article type
Paper

Suberin isolation from cork using ionic liquids: characterisation of ensuing products

R. Ferreira, H. Garcia, A. F. Sousa, M. Petkovic, P. Lamosa, C. S. R. Freire, A. J. D. Silvestre, L. P. N. Rebelo and C. S. Pereira, New J. Chem., 2012, 36, 2014
DOI: 10.1039/C2NJ40433H

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