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Issue 6, 2012
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Controlling the position of anions relative to a pentafluorophenyl group†

Michael Giese,a   Markus Albrecht,*a   Katharina Wiemer,a   Arto Valkonenb  and  Kari Rissanenb  
Author affiliations

* Corresponding authors

a Institut für Organische Chemie, RWTH Aachen, Landoltweg 1, 52074 Aachen, Germany
E-mail: markus.albrecht@oc.rwth-aachen.de
Fax: +49 241 809 2385
Tel: +49 241 809 4678

b Department of Chemistry, Nanoscience Center, University of Jyväskylä, Survontie 9, 40014 Jyväskylä, Finland
E-mail: kari.t.rissanen@jyu.fi
Fax: +358 14 260 2672
Tel: +358 50 562 3721

Abstract

The position of an anion above an electron-deficient arene can be controlled by the geometry of appended directing groups. Here a series of ammonium substituted pentafluorophenyl derivatives is investigated. The presented results are one step on the way to find the ideal structural features for an effective and superior receptor for anion–π studies.

Graphical abstract: Controlling the position of anions relative to a pentafluorophenyl group

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Article information

https://doi.org/10.1039/C2NJ40089H
Submitted
07 Feb 2012
Accepted
12 Mar 2012
First published
27 Mar 2012
New J. Chem., 2012,36, 1368-1372
Article type
Paper
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Controlling the position of anions relative to a pentafluorophenyl group

M. Giese, M. Albrecht, K. Wiemer, A. Valkonen and K. Rissanen, New J. Chem., 2012, 36, 1368
DOI: 10.1039/C2NJ40089H

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