Evidence of ionic liquid crystal properties for a DODA+ salt of the keplerate [Mo132O372(CH3COO)30(H2O)72]42−

Sébastien Floquet; Emmanuel Terazzi; Akram Hijazi; Laure Guénée; Claude Piguet; Emmanuel Cadot

doi:10.1039/C2NJ20923C

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Evidence of ionic liquid crystal properties for a DODA⁺ salt of the keplerate [Mo₁₃₂O₃₇₂(CH₃COO)₃₀(H₂O)₇₂]⁴²⁻†

Sébastien Floquet,*^a Emmanuel Terazzi,*^b Akram Hijazi,^ac Laure Guénée,^b Claude Piguet^b and Emmanuel Cadot^a

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* Corresponding authors

^a Institut Lavoisier de Versailles, UMR 8180, University of Versailles Saint-Quentin, 45 av. des Etats-Unis, 78035 Versailles, France
E-mail: sebastien.floquet@chimie.uvsq.fr
Fax: +33 139254381
Tel: +33 139254379

^b Department of Inorganic, Analytical and Applied Chemistry, University of Geneva, 30 quai E. Ansermet, CH-1211 Geneva 4, Switzerland
E-mail: emmanuel.terazzi@unige.ch
Fax: +41 223796830
Tel: +41 223796035

^c Lebanese University, Doctoral School of Science and Technology, Research Platform for Environmental Science (PRASE), Beirut, Lebanon

Abstract

Thermal studies of a DODA⁺ salt of the nanoscopic hollow sphere [Mo₁₃₂O₃₇₂(H₂O)₇₂(CH₃CO₂)₃₀]⁴²⁻ revealed ionic liquid crystalline properties, which were evidenced by Polarised Optical Microscopy, DSC and SA-XRD.

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Article information

DOI: https://doi.org/10.1039/C2NJ20923C
Article type: Letter
Submitted: 31 Oct 2011
Accepted: 26 Jan 2012
First published: 09 Feb 2012

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New J. Chem., 2012,36, 865-868

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Evidence of ionic liquid crystal properties for a DODA⁺ salt of the keplerate [Mo₁₃₂O₃₇₂(CH₃COO)₃₀(H₂O)₇₂]⁴²⁻

S. Floquet, E. Terazzi, A. Hijazi, L. Guénée, C. Piguet and E. Cadot, New J. Chem., 2012, 36, 865 DOI: 10.1039/C2NJ20923C

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