Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.


Issue 38, 2012
Previous Article Next Article

Auto-catalysed crosslinking for next-generation OLED-design

Author affiliations

Abstract

The production of solution-processed OLEDs requires materials suitable for subsequent multilayer deposition. In the current study, we present an autocatalytic method to crosslink a luminescent copper(I)-complex with a polymeric backbone, in which the emitter itself acts as catalyst. In a showcase reaction demonstrating this concept for the first time, we combined a highly luminescent binuclear copper(I)-complex with a polystyrene derivative in order to prove the potential of the protocol. The luminescence properties were only slightly affected by the crosslinking, while the general stability increased drastically, as proven by thermogravimetric analysis (TGA). OLED tests confirmed the fundamental suitability of the concept for device applications as well as for subsequent solution-based multilayer deposition.

Graphical abstract: Auto-catalysed crosslinking for next-generation OLED-design

Back to tab navigation

Supplementary files

Article information


Submitted
23 May 2012
Accepted
14 Aug 2012
First published
03 Sep 2012

J. Mater. Chem., 2012,22, 20786-20790
Article type
Paper

Auto-catalysed crosslinking for next-generation OLED-design

D. Volz, T. Baumann, H. Flügge, M. Mydlak, T. Grab, M. Bächle, C. Barner-Kowollik and S. Bräse, J. Mater. Chem., 2012, 22, 20786
DOI: 10.1039/C2JM33291D

Search articles by author

Spotlight

Advertisements