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Issue 10, 2012
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Vacuum-processable ladder-type oligophenylenes for organic–inorganic hybrid structures: synthesis, optical and electrochemical properties upon increasing planarization as well as thin film growth

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Abstract

A novel synthetic route to even-numbered ladder-type oligo(p-phenylene)s (LOPPs) carrying no solubilizing groups to facilitate vacuum-processing is presented. The influence of increasing bridging adjacent phenylene units on the optical and electrochemical properties is discussed in the series of p-sexiphenyl 6P, terfluorene 3F, and ladder-type sexiphenyl L6P. The influence of the extension of the π-system is taken into consideration as well. Furthermore it is shown that highly ordered thin films of L6P on alumina surfaces can be prepared by organic molecular beam deposition (OMBD).

Graphical abstract: Vacuum-processable ladder-type oligophenylenes for organic–inorganic hybrid structures: synthesis, optical and electrochemical properties upon increasing planarization as well as thin film growth

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Publication details

The article was received on 14 Nov 2011, accepted on 12 Dec 2011 and first published on 13 Jan 2012


Article type: Paper
DOI: 10.1039/C2JM15868J
Citation: J. Mater. Chem., 2012,22, 4383-4390
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    Vacuum-processable ladder-type oligophenylenes for organic–inorganic hybrid structures: synthesis, optical and electrochemical properties upon increasing planarization as well as thin film growth

    B. Kobin, L. Grubert, S. Blumstengel, F. Henneberger and S. Hecht, J. Mater. Chem., 2012, 22, 4383
    DOI: 10.1039/C2JM15868J

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