Novel organic–inorganic hybrid ferroelectric: bis(imidazolium) pentachloroantimonate(III), (C3N2H5)2SbCl5

Anna Piecha; Agata Białońska; Ryszard Jakubas

doi:10.1039/C1JM13597J

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Novel organic–inorganic hybrid ferroelectric: bis(imidazolium) pentachloroantimonate(iii), (C₃N₂H₅)₂SbCl₅†

Anna Piecha,*^a Agata Białońska^a and Ryszard Jakubas^a

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* Corresponding authors

^a Faculty of Chemistry, University of Wrocław, F. Joliot-Curie 14, Wrocław, Poland
E-mail: anna.piecha@chem.uni.wroc.pl
Fax: +48 71 328 2348
Tel: +48 71 375 7288

Abstract

Electric permittivity, reaching ca. 4800 units at T_c, of the first haloantimonate(III) ferroelectric with R₂MX₅ composition characterized by unprecedented SbCl₅ chains of cis-connected octahedra results from the mixed ‘order–disorder’ and ‘displacive’ mechanism of the phase transition.

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Article information

DOI: https://doi.org/10.1039/C1JM13597J
Article type: Communication
Submitted: 28 Jul 2011
Accepted: 05 Nov 2011
First published: 23 Nov 2011

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J. Mater. Chem., 2012,22, 333-336

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Novel organic–inorganic hybrid ferroelectric: bis(imidazolium) pentachloroantimonate(III), (C₃N₂H₅)₂SbCl₅

A. Piecha, A. Białońska and R. Jakubas, J. Mater. Chem., 2012, 22, 333 DOI: 10.1039/C1JM13597J

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Journal of Materials Chemistry