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Issue 12, 2012
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Easily removable olefin metathesis catalysts

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Abstract

A small family of olefin metathesis catalysts bearing a polar quaternary ammonium group is described. The presence of this group allows for efficient separation of ruthenium impurities after the reaction. Application of catalysts 9 and 11 leads to organic products of high purity, which exhibit surprisingly low ruthenium contamination levels (usually below 5 ppm) after a simple and inexpensive purification step.

Graphical abstract: Easily removable olefin metathesis catalysts

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Article information


Submitted
02 Jul 2012
Accepted
27 Sep 2012
First published
01 Oct 2012

Green Chem., 2012,14, 3264-3268
Article type
Communication

Easily removable olefin metathesis catalysts

K. Skowerski, C. Wierzbicka, G. Szczepaniak, Ł. Gułajski, M. Bieniek and K. Grela, Green Chem., 2012, 14, 3264
DOI: 10.1039/C2GC36015B

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