Issue 2, 2012
From the journal:

Green Chemistry

Aqueous solutions of facial amphiphilic carbohydrates as sustainable media for organocatalyzed direct aldol reactions†

Ana Bellomo,ab   Richard Daniellou‡*ab  and  Daniel Plusquellec*ab  

* Corresponding authors

a Ecole Nationale Supérieure de Chimie de Rennes, CNRS, UMR 6226, Avenue du Général Leclerc, CS 50837, Rennes Cedex 7, France
E-mail: richard.daniellou@univ-orleans.fr, daniel.plusquellec@ensc-rennes.fr
Fax: (+)33-2-23-23-80-46
Tel: (+)33-2-23-23-80-96

b Université Européenne de Bretagne,

Abstract

The organocatalyzed direct aldol reaction was efficiently performed in aqueous solutions of facial amphiphilic carbohydrates with high diastereoselectivity and yield. Such sustainable media in addition with the use of 2% catalyst loading paves the way for the development of original ecofriendly procedures through non-covalent induction.

Graphical abstract: Aqueous solutions of facial amphiphilic carbohydrates as sustainable media for organocatalyzed direct aldol reactions

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Article information

DOI
https://doi.org/10.1039/C1GC16326D
Article type
Communication
Submitted
25 Oct 2011
Accepted
17 Nov 2011
First published
12 Dec 2011

Green Chem., 2012,14, 281-284

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Aqueous solutions of facial amphiphilic carbohydrates as sustainable media for organocatalyzed direct aldol reactions

A. Bellomo, R. Daniellou and D. Plusquellec, Green Chem., 2012, 14, 281 DOI: 10.1039/C1GC16326D

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