Issue 2, 2012
From the journal:

Green Chemistry

Synthesis of selenol esters from diorganyl diselenides and acyl chlorides under solvent-free conditions and microwave irradiation†

Marcelo Godoi,a   Eduardo W. Ricardo,a   Giancarlo V. Botteselle,a   Fabio Z. Galetto,ab   Juliano B. Azeredoa  and  Antonio L. Braga*a  

* Corresponding authors

a Departamento de Química, Universidade Federal de Santa Catarina, Florianópolis, SC, Brazil
E-mail: albraga@qmc.ufsc.br
Fax: +55-48 3721 6427
Tel: +55-48 3721 6844

b Departamento de Química, Universidade Federal de Santa Maria, Santa Maria, RS, Brazil
Fax: +55-55 3220 8998
Tel: +55-55 3220 8761

Abstract

Herein, we report an efficient, quick and eco-friendly new method for the synthesis of a variety of selenol esters. This novel solvent-free methodology gave good to excellent isolated yields of desired products after just 2 min under microwave irradiation. Furthermore, by using the same green approach, we were also able to synthesize selenocarbonates bearing interesting functionalities.

Graphical abstract: Synthesis of selenol esters from diorganyl diselenides and acyl chlorides under solvent-free conditions and microwave irradiation

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Article information

DOI
https://doi.org/10.1039/C1GC16243H
Article type
Paper
Submitted
06 Oct 2011
Accepted
18 Nov 2011
First published
04 Jan 2012

Green Chem., 2012,14, 456-460

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Synthesis of selenol esters from diorganyl diselenides and acyl chlorides under solvent-free conditions and microwave irradiation

M. Godoi, E. W. Ricardo, G. V. Botteselle, F. Z. Galetto, J. B. Azeredo and A. L. Braga, Green Chem., 2012, 14, 456 DOI: 10.1039/C1GC16243H

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