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Issue 10, 2012
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Boron-based electrolyte solutions with wide electrochemical windows for rechargeable magnesium batteries

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Abstract

Recently, we have developed a boron based electrolyte system with outstanding electrochemical performance, formed through the reaction of tri(3,5-dimethylphenyl)borane (Mes3B) and PhMgCl in THF, for rechargeable magnesium batteries. In this paper, the main components and equilibria of the unique boron based electrolyte solutions are identified by NMR, single-crystal XRD, etc. The results prove that the solutions contain various magnesium species, such as Mg2Cl3+, MgCl+, Ph2Mg and the tetracoordinated boron anion [Mes3BPh]. Fluorescence spectra and Raman spectroscopy analyses indicate that the high anodic stability (ca. 3.5 V vs. Mg reference electrode (RE)) of the Mes3B–(PhMgCl)2 electrolyte is attributed to the non-covalent interactions between the anion [Mes3BPh] and Ph2Mg. Furthermore, the air sensitivity of the boron based electrolyte and its electrochemical stability on the different current collectors are studied. Finally, the reversible electrochemical process of Mg intercalation into a Mo6S8 cathode confirms that the boron based electrolyte could be practically used in rechargeable Mg battery systems.

Graphical abstract: Boron-based electrolyte solutions with wide electrochemical windows for rechargeable magnesium batteries

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Publication details

The article was received on 11 Jun 2012, accepted on 21 Aug 2012 and first published on 21 Aug 2012


Article type: Paper
DOI: 10.1039/C2EE22509C
Citation: Energy Environ. Sci., 2012,5, 9100-9106
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    Boron-based electrolyte solutions with wide electrochemical windows for rechargeable magnesium batteries

    Y. Guo, F. Zhang, J. Yang, F. Wang, Y. NuLi and S. Hirano, Energy Environ. Sci., 2012, 5, 9100
    DOI: 10.1039/C2EE22509C

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