Issue 3, 2012

Emerging concepts in solid-state hydrogenstorage: the role of nanomaterials design

Abstract

This perspective highlights the state-of-the-art solid-state hydrogen storage and describes newly emerging routes towards meeting the practical demands required of a solid-state storage system. The article focuses both on the physical and chemical aspects of hydrogen storage. Common to both classes of storage material is the concept of nanostructure design to tailor kinetics and thermodynamics; whether this be control of functionalised porosity or crystalline growth on the nanoscale. In the area of chemical storage, different processing and nanostructuring techniques that have been employed to overcome the barriers of slow kinetics will be discussed in addition to new chemical systems that have emerged. The prospects of porous inorganic solids, coordination polymers (metal organic frameworks; MOFs) and other polymeric matrices for physical storage of hydrogen will be highlighted. Additionally the role of inorganic nanostructures as evolving materials “intermediate” between physical and chemical storage systems will be discussed and their place within the fine thermodynamic balance for optimum hydrogen uptake and release considered.

Graphical abstract: Emerging concepts in solid-state hydrogen storage: the role of nanomaterials design

Article information

Article type
Perspective
Submitted
11 Nov 2011
Accepted
26 Jan 2012
First published
26 Jan 2012

Energy Environ. Sci., 2012,5, 5951-5979

Emerging concepts in solid-state hydrogen storage: the role of nanomaterials design

H. Reardon, J. M. Hanlon, R. W. Hughes, A. Godula-Jopek, T. K. Mandal and D. H. Gregory, Energy Environ. Sci., 2012, 5, 5951 DOI: 10.1039/C2EE03138H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements