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Issue 43, 2012
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Carboxylated polymers functionalized by cyclodextrins for the stabilization of highly efficient rhodium(0) nanoparticles in aqueous phase catalytic hydrogenation

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Abstract

Rhodium(0) nanoparticles stabilized by a polymer containing carboxylate and β-cyclodextrin moieties have high stability and catalytic activity for aqueous hydrogenation reactions of olefins and aromatic substrates. This catalytic system can be recycled and reused without loss of activity. These high catalytic performances can be attributed to conjugated electrostatic interactions (carboxylate groups) and steric interactions (polymer structure and β-cyclodextrin moiety).

Graphical abstract: Carboxylated polymers functionalized by cyclodextrins for the stabilization of highly efficient rhodium(0) nanoparticles in aqueous phase catalytic hydrogenation

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Publication details

The article was received on 18 Jul 2012, accepted on 05 Sep 2012 and first published on 05 Sep 2012


Article type: Paper
DOI: 10.1039/C2DT31596C
Citation: Dalton Trans., 2012,41, 13359-13363
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    Carboxylated polymers functionalized by cyclodextrins for the stabilization of highly efficient rhodium(0) nanoparticles in aqueous phase catalytic hydrogenation

    S. Noël, B. Léger, R. Herbois, A. Ponchel, S. Tilloy, G. Wenz and E. Monflier, Dalton Trans., 2012, 41, 13359
    DOI: 10.1039/C2DT31596C

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