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Issue 28, 2012
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Aqueous biphasic hydroformylation in the presence of cyclodextrins mixtures: evidence of a positive synergistic effect

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Abstract

Mixtures of randomly methylated cyclodextrins of various sizes have been evaluated in the rhodium-catalysed hydroformylation of higher olefins in an aqueous biphasic medium. A marked positive non-linear effect on 1-tetradecene conversion is observed when the CD molar ratio in the mixture is modified. The formation of 2 : 1 ternary inclusion complexes between RAME-CDs and the olefin is supposed to be responsible for the extra conversion observed.

Graphical abstract: Aqueous biphasic hydroformylation in the presence of cyclodextrins mixtures: evidence of a positive synergistic effect

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Publication details

The article was received on 21 Mar 2012, accepted on 17 May 2012 and first published on 18 May 2012


Article type: Paper
DOI: 10.1039/C2DT30646H
Citation: Dalton Trans., 2012,41, 8643-8647
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    Aqueous biphasic hydroformylation in the presence of cyclodextrins mixtures: evidence of a positive synergistic effect

    M. Ferreira, F. Legrand, C. Machut, H. Bricout, S. Tilloy and E. Monflier, Dalton Trans., 2012, 41, 8643
    DOI: 10.1039/C2DT30646H

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