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Issue 24, 2012
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Dinuclear complexes of tetravalent cerium in an aqueous perchloric acid solution

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Abstract

Primary aquo species of tetravalent cerium (Ce(IV)) in perchloric acid has been identified as a single oxo-bridging dinuclear complex, not a mononuclear one, by extended X-ray absorption fine structure (EXAFS) spectroscopy combined with density functional theory (DFT) calculations.

Graphical abstract: Dinuclear complexes of tetravalent cerium in an aqueous perchloric acid solution

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Supplementary files

Article information


Submitted
13 Dec 2011
Accepted
10 Feb 2012
First published
08 Mar 2012

Dalton Trans., 2012,41, 7190-7192
Article type
Communication

Dinuclear complexes of tetravalent cerium in an aqueous perchloric acid solution

A. Ikeda-Ohno, S. Tsushima, C. Hennig, T. Yaita and G. Bernhard, Dalton Trans., 2012, 41, 7190
DOI: 10.1039/C2DT12406H

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