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Issue 12, 2012
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Highly active zinc alkyl cations for the controlled and immortal ring-opening polymerization of ε-caprolactone

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Abstract

Zinc alkyl cations supported by N,N-BIAN-type bidentate ligands were found to be highly active in the immortal ROP of ε-caprolactone to yield narrowly disperse and chain length-controlled poly(ε-caprolactone), whether in solution or bulk polymerization conditions.

Graphical abstract: Highly active zinc alkyl cations for the controlled and immortal ring-opening polymerization of ε-caprolactone

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Publication details

The article was received on 03 Dec 2011, accepted on 24 Jan 2012 and first published on 10 Feb 2012


Article type: Communication
DOI: 10.1039/C2DT12336C
Dalton Trans., 2012,41, 3377-3379

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    Highly active zinc alkyl cations for the controlled and immortal ring-opening polymerization of ε-caprolactone

    C. Romain, V. Rosa, C. Fliedel, F. Bier, F. Hild, R. Welter, S. Dagorne and T. Avilés, Dalton Trans., 2012, 41, 3377
    DOI: 10.1039/C2DT12336C

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