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Issue 22, 2012
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Tripodal europium complex with triangulenium dye: a model bifunctional metallo-organic system

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Abstract

A new tripodal ligand has been designed by coupling pyridyldicarbonyl binding strands with a triazatriangulenium platform (TATA). The complexation reaction with europium provides a C3-symmetrical mononuclear compound that is characterized with NMR, ESMS and qualitatively with single-crystal X-ray crystallography. In addition, photophysical studies of this dual emissive system have been performed, since the combination of the TATA fluorophore with trivalent lanthanides is of potential interest for the further development of imaging applications.

Graphical abstract: Tripodal europium complex with triangulenium dye: a model bifunctional metallo-organic system

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Supplementary files

Article information


Submitted
02 Dec 2011
Accepted
10 Apr 2012
First published
23 Apr 2012

Dalton Trans., 2012,41, 6777-6782
Article type
Paper

Tripodal europium complex with triangulenium dye: a model bifunctional metallo-organic system

J. Hamacek, C. Besnard, N. Mehanna and J. Lacour, Dalton Trans., 2012, 41, 6777
DOI: 10.1039/C2DT12332K

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