Issue 10, 2012
From the journal:

Dalton Transactions

Induction of trimeric [Mg3(OH)(CO2)6] in a porous framework by a desymmetrized tritopic ligand†

Quanguo Zhai,ab   Qipu Lin,a   Tao Wu,a   Shou-Tian Zheng,c   Xianhui Bu*c  and  Pingyun Feng*a  

* Corresponding authors

a Department of Chemistry, University of California, Riverside, CA, USA
E-mail: pingyun.feng@ucr.edu

b Key Laboratory of Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi’ an, Shaanxi, P. R. China

c Department of Chemistry and Biochemistry, California State University, Long Beach, CA, USA
E-mail: xbu@csulb.edu

Abstract

The use of a desymmetrized tritopic ligand with both carboxyl and pyridyl functionalities leads to the first occurrence of the [Mg3(μ3-OH)(CO2)6] trimer as the 3-D framework building block in a porous crystal that shows relatively high H2 uptake (1.37% at 77 K and 1 atm).

Graphical abstract: Induction of trimeric [Mg3(OH)(CO2)6] in a porous framework by a desymmetrized tritopic ligand

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Article information

DOI
https://doi.org/10.1039/C2DT12215D
Article type
Communication
Submitted
19 Nov 2011
Accepted
19 Dec 2011
First published
17 Jan 2012

Dalton Trans., 2012,41, 2866-2868

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Induction of trimeric [Mg3(OH)(CO2)6] in a porous framework by a desymmetrized tritopic ligand

Q. Zhai, Q. Lin, T. Wu, S. Zheng, X. Bu and P. Feng, Dalton Trans., 2012, 41, 2866 DOI: 10.1039/C2DT12215D

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