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Issue 14, 2012
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A series of isostructural mesoporous metal–organic frameworks obtained by ion-exchange induced single-crystal to single-crystal transformation

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Abstract

A series of metal–organic frameworks representing a non-interpenetrated framework analogue of MOF-14 have been synthesized by using two different linkers, 4,4′,4′′-benzene-1,3,5-triyl-benzoic acid (H3BTB) and 4,4′-bipyridine (Bpy). Interestingly, the transition metal ions in the paddle-wheel metal clusters could be exchanged by other transition metal ions via a direct single-crystal to single-crystal transformation. This post-synthesis route can be used for synthesis of isomorphous metal–organic frameworks that cannot be obtained by direct synthesis.

Graphical abstract: A series of isostructural mesoporous metal–organic frameworks obtained by ion-exchange induced single-crystal to single-crystal transformation

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Article information


Submitted
03 Nov 2011
Accepted
12 Jan 2012
First published
03 Feb 2012

Dalton Trans., 2012,41, 3953-3955
Article type
Communication

A series of isostructural mesoporous metal–organic frameworks obtained by ion-exchange induced single-crystal to single-crystal transformation

Q. Yao, J. Sun, K. Li, J. Su, M. V. Peskov and X. Zou, Dalton Trans., 2012, 41, 3953
DOI: 10.1039/C2DT12088G

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